Publications

Brook, David J.R.

Publications

Fleming, C.; Chung, D.; Ponce, S.; Brook, D. J. R.; DaRos, J.; Das, R.; Ozarowski, A.; Stoian, S. A., Valence tautomerism in a cobalt-verdazyl coordination compound. Chemical Commun. 2020, 56, 4400.

Stein, B. W.; Dickie, D. A.; Nedungadi, S.; Brook, D. J. R.; Shultz, D. A.; Kirk, M. L., Long-range spin dependent delocalization promoted by the pseudo Jahn-Teller effect. J. Chem. Phys. 2019, 151 (20), 201103.

Thurber, K. R.; Le, T.-N.; Changcoco, V.; Brook, D. J. R., Verdazyl-ribose: A new radical for solid-state dynamic nuclear polarization at high magnetic field. J. Mag. Res. 2018, 289, 122-131.

Brook, D. J. R.; Fleming, C.; Chung, D.; Richardson, C.; Ponce, S.; Das, R.; Srikanth, H.; Heindl, R.; Noll, B. C., An electron transfer driven magnetic switch: ferromagnetic exchange and spin delocalization in iron verdazyl complexes. Dalton Trans. 2018, 47, 6351-6360.

Le, T. N. T.; Trevisan, T.; Lieu, E.; Brook, D. J. R., Suzuki-Miyaura Coupling of Verdazyl Radicals. Eur. J. Org. Chem. 2017, 1125-1131.

Le, T.-N.; Grewal, H.; Changoco, V.; Truong, V.; Brook, D. J. R., Water soluble, chiral, verdazyl radicals derived from aldoses. Tetrahedron, 2016, 72 (41), 6368-6374.

Haller, B. C.; Chambers, D.; Cheng, R.; Chemistruck, V.; Hom, T. F.; Li, Z.; Nguyen, J.; Ichimura, A.; Brook, D. J. R., Oxidation of Electron Donor-Substituted Verdazyls: Building Blocks for Molecular Switches, J. Phys. Chem. A. 2015, 119, 10750-10760.

 Brook, D. J. R., Coordination Chemistry of Verdazyl Radicals, Comments on Inorganic Chemistry 2015, 35, 1-17.

Seber, G.; Brook, D. J. R.; Taylor, P. S.; Cassaro, R. A. A.; Lahti, P. M., Magnetostructural effects of changing spin unit structure and molecular connectivity on 1H-benzimidazole functionalized radicals. Polyhedron 2014,76, 36-44.

Brook, D. J. R., Keys To Building and Maintaining a Successful Undergraduate Research Program: Designing Research Projects for an Undergraduate Research Lab. In Developing and Maintaining a Successful Undergraduate Research Program, Chapp, T. W.; Benvenuto, M. A., Eds. 2013; Vol. 1156, pp 51-59.

Spectroscopy, Electrochemistry, and Nucleophilicity of Nickel and Cobalt Complexes of pyridine carboxaldehyde pyridyl hydrazone (papyH). Ly, H.; Oliverio O.; Brook, D. J. R.;. Inorganic Chimica Acta, 2011, 378 (1), 115-120

Molecular motion in zinc hydrazone grid complexes. Dutta, M.; Movasset, M.; Brook D. J. R.;, Oliver A.; Ward, D.; Supramolecular Chemistry, 2011, 23 (9), 632-643

Geometric control of ground state multiplicity in a copper(I) bis(verdazyl) complex. Brook, David J. R.*; Rogow, David; Hundley, Mike; Yee, Gordon; Wong, Janice; Tu, Khanh. Inorg. Chem. 2010, 49, 8573-8577.

Strong ferromagnetic metal-ligand exchange in a nickel bis(3,5-dipyridylverdazyl) complex.. Brook, David J. R.*; Richardson, Cardius; Haller, Benjamin C.; Hundley, Michael; Yee, Gordon T. Chem. Commun., 2010, 6590 - 6592

Structure-Property Relationships of Stable Free Radicals: Verdazyls with Electron-Rich Aryl Substituents. Chemistruck, V.; Chambers, D.; Brook, D. J. R.* J. Org. Chem. 2009, 74, 1850-1857.

Imidazole substituted oxoverdazyl radical as a mediator of intramolecular and intermolecular exchange interaction Norel, L.; Pointillart, F.; Train, C.; Chamoreau, L.-M.; Boubekeur, K.; Journaux, Y.; Brieger, A.; Brook, D. J. R., Inorg. Chem. 2008, 47, 2396-2403.

Radical-Radical Interaction through a Saturated Link: Methylenebis-6-oxoverdazyl. David J. R. Brook* and Gordon T. Yee, J. Org. Chem. 2006, 71, 4889-4895.

Self-Assembly, Structure and Solution Dynamics of Tetranuclear ZnII Hydrazone [2x2] Grid - Type Complexes, Mihail Barboiu, Mario Ruben, Georges Blasen, Nathalie Kyritsakas, Elizabeth Chacko, Manisha Dutta, Olga Radekovich, Kimberly Lenton, David J. R. Brook* and Jean-Marie Lehn*. Eur. J. Inor. Chem. 2006, 784

Synthesis of 1,5-diisopropyl substituted 6-oxoverdazyls. Emily C. Paré, David J. R. Brook* Aaron Brieger Mick Badik and Marie Schinke, Org. Biomol. Chem., 2005, 3, 4258

Coordinated Hydrazone Ligands as Nucleophiles:  Reactions of Fe(papy)2. Aaron Wood, Wasim Aris and David J. R. Brook*, Inorg. Chem, 2004, 43, 8355

Free radical complexes of copper(I): geometry and ground state Jon E. Stevens, David J. R. Brook* and Vincent W. Abeyta, Polyhedron, 2003, 22, 2241.

Spin distribution in copper(I) phosphine complexes of verdazyl radicals David J. R. Brook* and Vincent Abeyta J. Chem. Soc. Dalton Transactions, 2002, 4219.

Synthesis and Structure of di-μ-bromo-bis[(1,5-dimethyl-3-(2'-pyridyl)-6-oxoverdazyl) copper(I)] .D. J. R. Brook,* S. Fornell, B. Noll, G. Yee, and T. H. Koch, J. Chem. Soc. Dalton Transactions, 2000, 2019.

Coordination Chemistry of Verdazyl Radicals: Group 12 Metal (Zn, Cd, Hg) Complexes of 1,4,5,6-Tetrahydro-2,4-Dimethyl-6-(2'-pyridyl)-1,2,4,5-tetrazine-3(2H)-one (pvdH3) and 1,5-dimethyl-3-(2'-pyridyl)-6-oxoverdazyl (pvd) D. J. R. Brook,* S. Fornell, J. E. Stevens, B. Noll, T. H. Koch, and W. Eisfeld, Inorganic Chemistry, 2000, 39, 562.

Radicals, Metals and Magnetism. David J. R. Brook,* Science Progress, 1998, 81, 369.

Carbonyl and Thiocarbonyl Stabilized 1,4-dihydropyrazines: synthesis and characterization David J. R. Brook,* Bruce Noll and Tad H. Koch, J. Chem. Soc. Perkin Trans I, 1998, 289.

Dioxygen Oxidation of a Stable 1,4-Dihydropyrazine. David J. R. Brook and Tad H. Koch.* J. Org. Chem. 1997, 62, 6767

Structure and Properties of Some New Dihydropyrazine--Tetracyanoquinodimethane Charge Transfer Salts. David J. R. Brook and Tad H. Koch.* J. Mater. Chem. 1997, 7, 2381

Spin delocalization in the Copper(I) Complexes of Bis(verdazyl) Diradicals David J. R. Brook,* Vincent Lynch, Brenda Conklin and Marye Anne Fox. J. Am. Chem. Soc. 1997,119, 5155.

Structural Indicators of Electronic Interaction in the 1,1',5,5'-Tetramethyl-6,6'-dioxo-3,3'-biverdazyl Diradical. David J. R. Brook, Harold H. Fox, Vincent Lynch and Marye Anne Fox.* J. Phys. Chem. 1996, 100, 2066.

Disproportionation of diiron nonacarbonyl in THF: formation and structure of Fe(THF)4 [HFe3(CO)11]2. David J. R. Brook, Vincent Lynch and Tad H. Koch.* Inorg. Chem. 1995, 34, 5691.

Structural Characterization of Crystalline Zinc (II) and Palladium (II) Octakis(-decoxyethyl)porphyrin Thin Films. Dan Melamed, Bill Darlington, David J. R. Brook, Horng-Long Pan, Alan Campion* and Marye Anne Fox.* J. Phys. Chem. 1994, 98, 8971.

Synthesis, Structure, and Reactivity of an Antiaromatic, 2,5-Dicarboxy-stabilized 1,4-Dihydropyrazine. David J. R. Brook, R. Curtis Haltiwanger and Tad H. Koch.* J. Am. Chem. Soc. 1992, 114, 6017.

New Type of Charge Transfer Complex from an Antiaromatic Electron Donor. Possible Radical Cation Stabilization by the Captodative Effect. David J. R. Brook, R. Curtis Haltiwanger and Tad H. Koch.* J. Am. Chem. Soc. 1991, 113, 5910.